Joseph Mallord William Turner

Inscription by Turner: Notes from Nicholson’s ‘Dictionary of Practical and Theoretical Chemistry’; with Two Unrelated Diagrams


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Joseph Mallord William Turner 1775–1851
Graphite on paper
Support: 88 x 113 mm
Accepted by the nation as part of the Turner Bequest 1856
Turner Bequest CXXXV 56 a

Catalogue entry

The whole page is taken up with notes on chemistry in relation to colour:
Carthamus – Saffron – Alum yilds [sic] a | deep yellow precipitate. in caustic Alkali | lime deep yellow colour. [?W] grow well in | sandy soil. requires but little watering
Solution of Soap and Solution of Sulphat of | Magnesia – composition white indis in Boil | water Expressed oil and alco disolve [sic] it | when melted it forms a transparent mass | slightly yellow, very brittle. Oil and clay | by a solution of soap with alum gave a | flexible, indis in W A & O very readily | Enters into fusion when it makes a beautiful | transparent mass inclind to yellow
Without establishing their origin, Joyce Townsend interprets these notes as concerning the making of ‘yellow organic pigments’ by: ‘growing the plant, treating the relevant part, precipitating the dye onto a claybase, ie forming a laked pigment’.1
This is one of fourteen pages of notes on varnishes and colours resulting from chemical reactions between folio 62 verso (D09974) and folio 55 recto (D09959), working from the back of the sketchbook as now foliated. As discussed in the sketchbook’s Introduction,2 most are taken from William Nicholson’s 1808 Dictionary of Practical and Theoretical Chemistry, here beginning with the unpaginated entry on ‘Saffron (Bastard)’:
Alum forms with it a deep yellow precipitate in small quantity.
... If these flowers be put into a solution of caustic alkali, they become yellow, and the and the liquor which is pressed out is of a deep yellow colour.
Turner’s comments on soil and watering seem to be his own gloss on Nicholson’s lengthy description of the cultivation of saffron in Egypt and elsewhere. The next notes are from Nicholson’s entry on ‘Soap’:
The mixture of a solution of soap and a solution of sulphat of magnesia afforded a combination of the utmost whiteness. It is unctuous, dries with difficulty, and preserves its white colour after desiccation. It is insoluble in boiling water, but has nevertheless a decided taste of soap. Expressed oil, as well as alcohol, dissolves it in considerable Quantity. When water is added to the solution in the latter fluid, it becomes milky. This combination melts with a moderate heat, and forms a transparent mass, slightly yellow, and very brittle. ...

Matthew Imms
April 2014

Townsend 1992, p.7, with transcription (followed here with slight variations).
See also summary in Imms 2011, p.4.

Read full Catalogue entry

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